Priprava kvaternih soli N-etilmorfolina

master's thesis

• Title (english): Synthesis of N-ethylmorpholine quaternary salts
• Author: Marija Duvnjak
• Mentor: Jasna Vorkapic-Furac (mentor)
• Granter: University of Zagreb; Faculty of Food Technology and Biotechnology; (Department of Biochemical Engineering); (Laboratory for Cell Technology, Application and Biotransformations); Zagreb
• Defense date and country: 2009-04-03, Croatia
• Scientific / art field, discipline and subdiscipline: BIOTECHNICAL SCIENCES; Biotechnology

Abstract

Cilj ovog rada bila je sinteza monokvaternih i dikvaternih morfolinijevih ionskih tekućina koje su bile pripravljene reakcijama kvaternizacije N-etilmorfolina sa 1,3-dijodpropanom, 1,4-dijodbutanom i 1,6-dibromheksanom. U ovom radu reakcijom kvaternizacije N-etilmorfolina pripravljeno je pet (5) novih, do sada neobjavljenih, kvaternih soli. Strukture spojeva [1]-[5] odredene su pomoću podataka dobivenih IRspektroskopijom te 1H- i 13C- nuklearno-magnetskom rezonancijom. Za spoj [1] struktura je upotpunjena i kristalografskom analizom.

Abstract (english)

The goal of this work was synthesis of monoquaternary and bisquaternary morpholinium ionic liquids prepared by quaternization of N-ethylmorpholine with 1,3– diiodo- propane, 1,4-diiodobutane and 1,6-dibromohexane. In this work five (5) novel, yet not published, quaternary salts were synthesized by the quaternization of Nethylmorpholine. The structures of new compounds [1]-[5] were determined according to the data obtained by IR-spectroscopy as well as 1H- and 13C- nuclear magnetic resonance. For the compound [1] the structure was completed by crystallographic analysis.

• Keywords: ionske tekućine; N-etilmorfolin; reakcije kvaternizacije; mikrovalno zračenje
• Keywords (english): N-ethylmorpholine; ionic liquids; microwave irradiation; quaternization
• Language: croatian
• URN:NBN: urn:nbn:hr:159:539879
• Study programme: Title: Biotechnology; specializations in: Biochemical-Microbiology; Course: Biochemical-Microbiology; Study programme type: university; Study level: graduate; Academic / professional title: diplomirani inženjer biotehnologije; smjer biokemijsko-mikrobiološki (diplomirani inženjer biotehnologije; smjer biokemijsko-mikrobiološki)
• Type of resource: Text
• File origin: Born digital
• Access conditions: Access restricted to students and staff of home institution
• Created on: 2017-08-31 08:08:37